| Chancel Mbemba | R.S.C. Anderlecht | 2013–2015 | 63 | 6 |
| Yannick Bolasie | R.S.C. Anderlecht | 2019–2019 | – | – |
| Dieumerci Mbokani | R.S.C. Anderlecht, Standard Liège | 2006–2013 | 149 | 77 |
| Noah Sadiki now | Royale Union Saint-Gilloise | 2023–now | – | – |
| Theo Bongonda | K.R.C. Genk, S.V. Zulte Waregem | 2013–2022 | 135 | 40 |
| Mbo Mpenza | Royal Excelsior Mouscron, R.S.C. Anderlecht, Standard Liège, K.V. Kortrijk | 1993–2008 | 303 | 113 |
| Dylan Batubinsika now | Royal Antwerp F.C. | ?–now | – | – |
| Edo Kayembe | R.S.C. Anderlecht | 2017–2020 | – | – |
| Fabrice Nsakala | R.S.C. Anderlecht | 2013– | – | – |
| Gaby Mudingayi | Royale Union Saint-Gilloise, KAA Gent | 1998–2004 | 98 | 1 |
| Neeskens Kebano | K.R.C. Genk, Royal Charleroi S.C. | 2013– | 77 | 36 |
| Junior Kabananga | R.S.C. Anderlecht, Cercle Brugge K.S.V., Beerschot A.C. | 2010–2015 | 72 | 14 |
| Joris Kayembe now | K.R.C. Genk | 2023–now | – | – |
| Paul-Jose M'Poku | Standard Liège | 2011–2015 | 90 | 19 |
| Aaron Leya Iseka | R.S.C. Anderlecht | 2014– | – | – |
| Chris Mavinga | K.R.C. Genk | 2010–2011 | 9 | 0 |
| Christian Luyindama | Standard Liège | ?– | – | – |
| Jeremy Bokila | S.V. Zulte Waregem | 2010–2013 | 25 | 2 |
| Mushaga Bakenga | Club Brugge K.V., Cercle Brugge K.S.V. | 2012–2013 | 35 | 8 |
| Parfait Mandanda | Royal Charleroi S.C. | 2011– | 98 | 0 |
| Roger Lukaku | KV Mechelen, R.F.C. Seraing, Beerschot A.C. | 1993–1998 | 88 | 36 |
| Arnaud Lusamba | Cercle Brugge K.S.V. | 2018–2019 | 25 | 0 |
| Jordan Botaka | KAA Gent, Club Brugge K.V., Royal Charleroi S.C. | 2012–2023 | 0 | 0 |
| Landry Mulemo | Sint-Truidense V.V., Standard Liège, K.V. Kortrijk | 2004–2015 | 178 | 2 |
| Jackson Muleka now | Standard Liège | 2020–now | – | – |
| Eugène Kabongo | R.S.C. Anderlecht, R.F.C. Seraing | 1983–1987 | 36 | 21 |
| Joël Sami | S.V. Zulte Waregem | 2015– | – | – |
| Dieumerci Ndongala | KAA Gent, Royal Charleroi S.C. | 2014– | – | – |
| Geoffrey Mujangi Bia | Standard Liège, Royal Charleroi S.C. | 2006–2015 | 147 | 34 |
| Mario Stroeykens now | R.S.C. Anderlecht | 2020–now | 1 | 0 |
| Yves Ma-Kalambay | KV Mechelen, Royal Antwerp F.C. | 2011–2015 | 5 | 0 |
| Hervé Kage | Royale Union Saint-Gilloise, R.S.C. Anderlecht, Royal Charleroi S.C., KAA Gent, K.R.C. Genk, K.V. Kortrijk | 2007–2020 | 249 | 35 |
| Michel-Ange Balikwisha now | Standard Liège | 2020–now | – | – |
| Nill De Pauw now | Royal Antwerp F.C., S.V. Zulte Waregem | 2017–now | – | – |
| Mulopo Kudimbana | Royale Union Saint-Gilloise, R.S.C. Anderlecht, Royal Antwerp F.C., Cercle Brugge K.S.V. | 2005– | 91 | 0 |
| Mulota Kabangu | R.S.C. Anderlecht | 2012–2012 | 12 | 3 |
| Wilson Kamavuaka | KV Mechelen | 2013–2014 | 18 | 3 |
| Zola Matumona | R.A.E.C. Mons | 2009–2014 | 9 | 0 |
| Benjamin Mokulu | Royale Union Saint-Gilloise, KV Mechelen | 2008–2015 | 41 | 9 |
| Ilombe Mboyo | KAA Gent, K.R.C. Genk, Royal Charleroi S.C., K.V. Kortrijk | 2008– | 113 | 22 |
| Julien Kialunda | Royale Union Saint-Gilloise, R.S.C. Anderlecht | 1960–1973 | – | – |
| Mbenza Bedi | R.S.C. Anderlecht | 2012–2013 | 14 | 0 |
| Rocky Bushiri now | KV Mechelen | 2020–now | – | – |
| William Balikwisha now | Oud-Heverlee Leuven, Standard Liège, Cercle Brugge K.S.V. | 2018–now | – | – |
| Lynel Kitambala | Royale Union Saint-Gilloise, Royal Charleroi S.C. | 2014– | 28 | 5 |
| Nzelo Hervé Lembi | Club Brugge K.V., Beerschot A.C. | 1995–2009 | 151 | 15 |
| Dieudonné Kalulika | Sint-Truidense V.V. | 2007–2007 | 7 | 0 |
| Elos Elonga-Ekakia | R.S.C. Anderlecht, Club Brugge K.V. | 1998–2002 | 48 | 12 |
| Joachim Mununga | R.A.E.C. Mons, KV Mechelen, Standard Liège, Beerschot A.C. | 2008– | 141 | 44 |
| Michel Ngonge | KAA Gent, R.F.C. Seraing | 1989–1992 | 23 | 7 |
| Papi Kimoto | Sint-Truidense V.V., Standard Liège | 2002–2005 | 37 | 3 |
| Tristan Muyumba | Cercle Brugge K.S.V. | ?– | – | – |
| Bavon Tshibuabua | Standard Liège, Beerschot A.C. | 2009– | 37 | 1 |
| Christian Kinkela | Royale Union Saint-Gilloise | 2003–2004 | 9 | 0 |
| Emeka Mamale | Royal Charleroi S.C. | ?– | – | – |
| Jeanvion Yulu-Matondo | K.V.C. Westerlo, Club Brugge K.V. | 2005–2013 | 56 | 11 |
| Léon Mokuna | KAA Gent, K.S.V. Waregem | 1957–1966 | – | – |
| Richard Kule Mbombo | Beerschot A.C. | ?– | – | – |
| Ali Lukunku | KAA Gent, R.A.E.C. Mons, Standard Liège | 1998–2008 | 60 | 22 |
| Eric Bokanga | Standard Liège | 2010–2010 | 13 | 1 |
| Ibrahim Somé Salombo | F.C. Verbroedering Dender Eendracht Hekelgem, Oud-Heverlee Leuven, Sint-Truidense V.V. | 2009–2015 | 37 | 13 |
| Jean-Marc Makusu | Standard Liège | 2014–2014 | – | – |
| Jean-Paul Boeka-Lisasi | KV Mechelen | ?– | – | – |
| Mike Mampuya | K.R.C. Genk | 2002–2003 | 0 | 0 |
| Olivier Nzuzi | Royal Excelsior Mouscron, Cercle Brugge K.S.V. | 1999–2002 | 64 | 10 |
| Pieter Mbemba | KV Mechelen | 2008–2009 | 1 | 0 |
| Andréa Mbuyi-Mutombo | Sint-Truidense V.V., Standard Liège, S.V. Zulte Waregem, Cercle Brugge K.S.V. | 2008–2012 | 52 | 5 |
| Danny Mansoni Ngombo | Royal Charleroi S.C. | ?– | – | – |
| John Buana N'Galula | K.F.C. Lommel S.K. | 1993–1995 | – | – |
| John Tshibumbu | Royal Charleroi S.C. | 2010–2012 | 4 | 0 |
| Nicodème Kabamba | Standard Liège | ?– | – | – |
| Patrick Dimbala | KAA Gent, F.C. Verbroedering Dender Eendracht Hekelgem, Royal Excelsior Mouscron | 2002– | 115 | 47 |
| Fabrice Lokembo-Lokaso | RAAL La Louvière, Royal Charleroi S.C. | 2002–2011 | 41 | 0 |
| Fabrice Omonga | RAAL La Louvière, Standard Liège, Oud-Heverlee Leuven, Royal Charleroi S.C. | 2007– | 36 | 2 |
| Freddy Mombongo-Dues | R.A.E.C. Mons, Standard Liège, Royal Antwerp F.C. | 2011– | 51 | 14 |
| Gabriel Ngalula | R.S.C. Anderlecht, Standard Liège, R.A.E.C. Mons | 2001–2007 | 34 | 1 |
| Jacques Kingambo | Sint-Truidense V.V., R.F.C. Seraing | 1984–1992 | – | – |
| Paul Bonga Bonga | Standard Liège, Royal Charleroi S.C. | 1957–1967 | – | – |
| Yves Angani | K.R.C. Genk | 2012–2013 | – | – |
| Edouard Kabamba | Standard Liège | 2007–2011 | 5 | 0 |
| Lionel Nshole Makondi | KV Mechelen | 2014– | – | – |
| Marlin Piana | Sint-Truidense V.V. | 2004–2004 | 5 | 0 |
| Muscal Mvuezolo | Royale Union Saint-Gilloise, R.S.C. Anderlecht, KV Mechelen | 1995–2007 | 61 | 2 |
| Pierre Mwana Kasongo | KAA Gent | 1965–1967 | – | – |
| Richard Mapuata N'Kiambi | Standard Liège | 1985–1986 | – | – |
| Bibey Mutombo | R.F.C. Seraing | ?– | – | – |
| Christian Landu-Tubi | R.A.E.C. Mons, KV Mechelen, Standard Liège, K.V. Kortrijk | 2002–2008 | 74 | 26 |
| Cédric Mitu | S.V. Zulte Waregem | 2014– | – | – |
| Fabrice Mvemba | F.C. Verbroedering Dender Eendracht Hekelgem | 2007–2009 | 11 | 0 |
| Jean-Paul Kielo-Lezi | F.C. Verbroedering Dender Eendracht Hekelgem, KV Mechelen, Sportkring Beveren | 2006– | 23 | 2 |
| Jules Ahoka now | Royal Antwerp F.C. | 2026–now | 3 | 0 |
| Mbala Henri Balenga | KAA Gent | ?– | – | – |
| Ndama Bapupa | Cercle Brugge K.S.V. | 2001–2002 | – | – |
| Olivier Mukendi | Royale Union Saint-Gilloise, R.S.C. Anderlecht, Cercle Brugge K.S.V. | 2008–2013 | 32 | 10 |
| Raoul Ngadrira | F.C. Verbroedering Dender Eendracht Hekelgem, KV Mechelen | 2008–2013 | 36 | 15 |
| Adaon Kalalla | R.S.C. Anderlecht | 2007–2009 | 0 | 0 |
| Dandou Kibonge Selenge | Royal Charleroi S.C. | ?– | – | – |
| Franck Nkela | R.A.E.C. Mons | 2008–2009 | 2 | 0 |
| Freddy Mulongo | Standard Liège | ?– | – | – |
| Gaël Kakudji | Royal Antwerp F.C. | 2018–2020 | – | – |
| Jean-Baptiste Yakassongo | Royal Excelsior Mouscron | 2008–2010 | 1 | 0 |
| Bienvenu Boyata | Royale Union Saint-Gilloise | ?– | – | – |
| Gauthier Madjo-Matsingi | Royal Antwerp F.C. | ?– | – | – |
| Kuyangana Makukula | R.F.C. Seraing | 1985–1986 | 12 | 1 |
| Noah Makanza now | KV Mechelen | 2025–now | – | – |
| Pombolo Sadi Wa | R.F.C. Seraing | 1983–1985 | – | – |